So the syntax error comes from the bash. You are trying to execute the ini file which is not an executable.
Please post content of /home/pi/.cache/lxsession/LXDE-pi/run.log file
You can use MobaXTerm or WinSCP applications which have embedded SFTP client that allows to access files on Pi directly from your computer.
Please post content of /home/pi/.cache/lxsession/LXDE-pi/run.log file
You can use MobaXTerm or WinSCP applications which have embedded SFTP client that allows to access files on Pi directly from your computer.